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91.
92.
Weak Ligand‐Field Effect from Ancillary Ligands on Enhancing Single‐Ion Magnet Performance 下载免费PDF全文
Yin‐Shan Meng Prof. Dr. Yi‐Quan Zhang Prof. Dr. Zhe‐Ming Wang Prof. Dr. Bing‐Wu Wang Prof. Dr. Song Gao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(36):12724-12731
A series of bis‐pentamethylcyclopentadienyl‐supported Dy complexes containing different ancillary ligands were synthesized and characterized. Magnetic studies showed that 1 Dy [Cp*2DyCl(THF)], 1 Dy’ [Cp*2DyCl2K(THF)]n, 2 Dy [Cp*2DyBr(THF)], 3 Dy [Cp*2DyI(THF)] and 4 Dy [Cp*2DyTp] (Tp=hydrotris(1‐pyrazolyl)borate) were single‐ion magnets (SIMs). The 1D dysprosium chain 1 Dy’ exhibited a hysteresis at up to 5 K. Furthermore, 3 Dy featured the highest energy barrier (419 cm?1) among the complexes. The effects of ancillary ligands on single‐ion magnetic properties were studied by experimental, ab initio calculations and electrostatic analysis methods in detail. These results demonstrated that the QTM rate was strongly dependent on the ancillary ligands and that a weak equatorial ligand field could be beneficial for constructing Dy‐SIMs. 相似文献
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94.
Existing literature regarding the natural hedge potential that arises from combining different longevity-linked liabilities typically does not address the question how changes in the liability mix can be obtained. We consider firms who aim to exploit the benefits of natural hedge potential by redistributing their risks, and characterize the risk redistributions that will arise when the parties bargain for a redistribution of risk that weakly benefits them all. We analyze the effects of heterogeneity in the beliefs regarding the probability distribution of future mortality rates on the properties of these risk redistributions, and provide a numerical illustration for a case where an insurer with a portfolio of term assurance contracts and a pension fund with a portfolio of life annuities redistribute their risks. 相似文献
95.
Chunxiao Ding Yun Sun Yuanguo Zhu 《Mathematical Methods in the Applied Sciences》2017,40(14):5079-5094
A new mathematical model included an exposed compartment is established in consideration of incubation period of schistosoma in human body. The basic reproduction number is calculated to illustrate the threshold of disease outbreak. The existence of the disease free equilibrium and the endemic equilibrium are proved. Studies about stability behaviors of the model are exploited. Moreover, control measure assessments are investigated in order to seek out effective control interventions for anti‐schistosomiasis. Then, the corresponding optimal control problem according to the model is presented and solved. Theoretical analyses and numerical simulations induce several prevention and control strategies for anti‐schistosomiasis. At last, a discussion is provided about our results and further work. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
96.
Xiuwen Li Zhenhai Liu C. C. Tisdell 《Mathematical Methods in the Applied Sciences》2017,40(12):4548-4559
The aim of this paper is to deal with the existence of mild solutions and exact controllability for a class of fractional evolution inclusions with damping (FEID, for short) in Banach spaces. Firstly, we provide the representation of mild solutions for FEID by applying the method of Laplace transform and the theory of (α,κ)‐regularized families of operators. Next, we are concerned with the existence and exact controllability of FEID under some suitable sufficient conditions by using the method of measure of noncompactness and an appropraite fixed point theorem. Finally, an application to nonlinear partial differential equations with temporal fractional derivatives is presented to illustrate the effectiveness of our main results. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
97.
Two homoclinic solutions for a nonperiodic fourth‐order differential equation without coercive condition 下载免费PDF全文
In this paper, we investigate the existence of homoclinic solutions for a class of fourth‐order nonautonomous differential equations where w is a constant, and . By using variational methods and the mountain pass theorem, some new results on the existence of homoclinic solutions are obtained under some suitable assumptions. The interesting is that a(x) and f(x,u) are nonperiodic in x,a does not fulfil the coercive condition, and f does not satisfy the well‐known (AR)‐condition. Furthermore, the main result partly answers the open problem proposed by Zhang and Yuan in the paper titled with Homoclinic solutions for a nonperiodic fourth‐order differential equations without coercive conditions (see Appl. Math. Comput. 2015; 250:280–286). Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
98.
A sustainable synthesis of biomass carbon sheets as excellent performance sodium ion batteries anode
Biomass-derived carbon (BMC) materials have attracted much attention due to their high performance and properties of abundant source. Herein, biomass carbon sheets (BMCS) from wheat straws had been successfully synthesized via a facile high temperature carbonization and expansion processes. The morphology of BMCS keeps the natural honeycomb-like shape of the cross section and the hollow tubular array structure of the vertical section with rich pores, which provides low-resistant ion channels to support fast diffusion. The (002) crystal plane reveals that the intercalation distance of carbon sheets is 0.383 nm larger than that graphite (0.335 nm), which benefits the larger sodium ion de/intercalation. By comparing different carbonization temperatures, wheat straws carbonized at 1200 °C (BMCS-1200) with well graphite microcrystallites show more excellent sodium ion storage performance than that of 900 °C (BMC-900). BMCS-1200 shows a stable reversible capacity of 221 mAh g?1 after 200 cycles at 0.05 A g?1, while BMC-900 is 162 mAh g?1 after 100 cycles. And it also exhibits better rate capability (220, 109 mAh g?1) than that of BMC-900 (125, 77 mAh g?1) at 0.2 and 1 A g?1, respectively. Finally, it delivers 89 mAh g?1 stable capacity after 1400 cycles at 1 A g?1 to prove its excellent long-term cycling stability. 相似文献
99.
A concept for light-powered visual detection of glucose is developed. The detection mechanism is based on pairing a photo-active anode with an electrochromic counter electrode. The photoelectrochemical reaction changes the oxidation state of the analyte, leading to a change in the color of the electrochromic material, which makes visual detection possible. All of the electrical charge required to change the color of the electrochromic material is supplied by the photoelectrochemical reaction powered by visible light, so no conventional energy source is required. The proposed system consists of hematite modified with nickel hydroxide (Ni(OH)2) as the photoanode, and Prussian blue deposited on a fluorine-doped tin oxide electrode as the electrochromic cathode. Under illumination, photo-oxidation of glucose at the photoanode is followed by reduction of Prussian blue to Prussian white at the cathode. The presence of glucose can therefore be detected visually as decolorization of Prussian blue occurs. 相似文献
100.
Molecular self-assembly offers a promising route to the preparation of advanced materials for the construction of novel chiral sensing devices, and the inspiration for the development of such systems is often derived from simple biological models. Diphenylalanine (FF), an extensively studied short peptide, can self-assemble into highly ordered nano-/micro-structures. Here we report the electrochemical recognition of tryptophan enantiomers using three FF self-assembled structures produced in the presence of graphene quantum dots (GQDs), chitosan (CS) and cetyltrimethylammonium bromide (CTAB). Although the difference in the peak potentials of the enantiomers is very small, enantiomeric differences can be detected by the magnitude of the DPV current signals. The recognition efficiencies of the three self-assembled materials are different, due to the different structures formed during the self-assembly process. 相似文献